Dichloridobis(thio-urea-κS)nickel(II).
Identifieur interne : 000211 ( Main/Exploration ); précédent : 000210; suivant : 000212Dichloridobis(thio-urea-κS)nickel(II).
Auteurs : Hafid Zouihri [Maroc]Source :
- Acta crystallographica. Section E, Structure reports online [ 1600-5368 ] ; 2012.
Abstract
The title complex, [NiCl(2)(CH(4)N(2)S)(2)], has been synthesized from the previously reported (diamino-methyl-idene)sulfonium chloride-thio-urea (3/2) salt [Zouihri (2012b ▶). Acta Cryst. E68, o257]. The Ni(II) ion is coordinated in a distorted tetra-hedral geometry by two mol-ecules of thio-urea [Ni-S = 2.3079 (7) and 2.3177 (6) Å] and two chloride anions [Ni-Cl = 2.2516 (7) and 2.2726 (7) Å]. The bond angles at the Ni atom lie between 96.69 (2) and 115.40 (3)°, while the dihedral angle between the mean planes of the two thio-urea ligands is 6.36 (15)°. The crystal structure is characterized by intra- and inter-molecular N-H⋯Cl hydrogen bonds, which lead to the formation of two-dimensional networks lying parallel to the ab plane. The networks are linked via classical N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional arrangement.
DOI: 10.1107/S1600536812006174
PubMed: 22412454
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 000079
- to stream PubMed, to step Curation: 000079
- to stream PubMed, to step Checkpoint: 000079
- to stream Ncbi, to step Merge: 000069
- to stream Ncbi, to step Curation: 000069
- to stream Ncbi, to step Checkpoint: 000069
- to stream Main, to step Merge: 000216
- to stream Main, to step Curation: 000211
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Dichloridobis(thio-urea-κS)nickel(II).</title><author><name sortKey="Zouihri, Hafid" sort="Zouihri, Hafid" uniqKey="Zouihri H" first="Hafid" last="Zouihri">Hafid Zouihri</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire Privé de Cristallographie (LPC), Kénitra, Morocco.</nlm:affiliation><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire Privé de Cristallographie (LPC), Kénitra</wicri:regionArea><wicri:noRegion>Kénitra</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2012">2012</date><idno type="RBID">pubmed:22412454</idno><idno type="pmid">22412454</idno><idno type="doi">10.1107/S1600536812006174</idno><idno type="wicri:Area/PubMed/Corpus">000079</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000079</idno><idno type="wicri:Area/PubMed/Curation">000079</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000079</idno><idno type="wicri:Area/PubMed/Checkpoint">000079</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000079</idno><idno type="wicri:Area/Ncbi/Merge">000069</idno><idno type="wicri:Area/Ncbi/Curation">000069</idno><idno type="wicri:Area/Ncbi/Checkpoint">000069</idno><idno type="wicri:Area/Main/Merge">000216</idno><idno type="wicri:Area/Main/Curation">000211</idno><idno type="wicri:Area/Main/Exploration">000211</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Dichloridobis(thio-urea-κS)nickel(II).</title><author><name sortKey="Zouihri, Hafid" sort="Zouihri, Hafid" uniqKey="Zouihri H" first="Hafid" last="Zouihri">Hafid Zouihri</name><affiliation wicri:level="1"><nlm:affiliation>Laboratoire Privé de Cristallographie (LPC), Kénitra, Morocco.</nlm:affiliation><country xml:lang="fr">Maroc</country><wicri:regionArea>Laboratoire Privé de Cristallographie (LPC), Kénitra</wicri:regionArea><wicri:noRegion>Kénitra</wicri:noRegion></affiliation></author></analytic><series><title level="j">Acta crystallographica. Section E, Structure reports online</title><idno type="eISSN">1600-5368</idno><imprint><date when="2012" type="published">2012</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The title complex, [NiCl(2)(CH(4)N(2)S)(2)], has been synthesized from the previously reported (diamino-methyl-idene)sulfonium chloride-thio-urea (3/2) salt [Zouihri (2012b ▶). Acta Cryst. E68, o257]. The Ni(II) ion is coordinated in a distorted tetra-hedral geometry by two mol-ecules of thio-urea [Ni-S = 2.3079 (7) and 2.3177 (6) Å] and two chloride anions [Ni-Cl = 2.2516 (7) and 2.2726 (7) Å]. The bond angles at the Ni atom lie between 96.69 (2) and 115.40 (3)°, while the dihedral angle between the mean planes of the two thio-urea ligands is 6.36 (15)°. The crystal structure is characterized by intra- and inter-molecular N-H⋯Cl hydrogen bonds, which lead to the formation of two-dimensional networks lying parallel to the ab plane. The networks are linked via classical N-H⋯Cl and N-H⋯S hydrogen bonds, forming a three-dimensional arrangement.</div></front></TEI><affiliations><list><country><li>Maroc</li></country></list><tree><country name="Maroc"><noRegion><name sortKey="Zouihri, Hafid" sort="Zouihri, Hafid" uniqKey="Zouihri H" first="Hafid" last="Zouihri">Hafid Zouihri</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000211 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000211 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= NickelMaghrebV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:22412454
|texte= Dichloridobis(thio-urea-κS)nickel(II).
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:22412454" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a NickelMaghrebV1
| This area was generated with Dilib version V0.6.27. |  |